path of valor : Seduction Not counting all shards

[Yamiray]

This may be a bug or how its was intended but here is what I noticed

this Morning I start by winning 23 Shards for Dolly then got 12 for Alt. Mani and 20 for Ghostly Past Jezebel

these being all legendary would be times 6

which should total 330 but is only totaling 306

after checking my records my Dolly before winning the 23 was at 81, so it was over by 4. that times 6 is 24 subtract 330 gives me my 306. 
so do shards you get that are over 100 not count towards this new event?

[Kaitana]

Path of valor is a new feature, not very well-know (by me, at least). But it seems you are right guessing only the shards before you reach 100 count in the path of valor (technically, they are the only shards you earn, the ones after 100 are converted and are not shards anymore)